Auto-relay catalysis for the oxidative carboxylation of alkenes into cyclic carbonates by a MOF catalyst

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Green Chem., 2025, Advance Article
DOI: 10.1039/D4GC06360K, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ha Phan, Pol de la Cruz-Sánchez, María Jesús Cabrera-Afonso, Belén Martín-Matute
In this study, we present the preparation and application of a new manganoporphyrin Hf-MOF catalyst, Hf-PCN-222(Mn) for the direct oxidative carboxylation of alkenes with CO2, leading to the effective formation of cyclic organic carbonates (COCs).
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