TBAF-catalyzed inverse vulcanization under mild conditions enabling synthesis of refractive indexing, ultraviolet blocking and light transmiting sulfur-rich polymers

Green Chem., 2025, 27,1974-1983
DOI: 10.1039/D4GC05827E, Communication

Xing-Rui Cao, Xiao-Jun Liu, Wei-Ping Li, Dong-Ping Chen, Tom Hasell, Xiaofeng Wu, Xi-Cun Wang, Zheng-Jun Quan
We present a tetrabutylammonium fluoride (TBAF)-catalyzed inverse vulcanization (IV) process that extends the methodology for anionic IV polymerisation under mild conditions and broadens the potential application areas of the resulting polymers.
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