General and chemoselective reduction of phosphine oxides by an enhanced oxophilic competition mechanism

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00477B, Paper
Mengyao You, Ziwei Zhang, Chao Chen, Zhichao Mei, Xinxin Zhang, Jiang Bai, Haiyang Huang, Qiang Xiao
Efficient organocatalytic PO reduction using commercial catalysts and inexpensive silanes under mild conditions. Exceptional chemoselectivity preserves reducible groups, offering scalable industrial potential for phosphine oxide recycling.
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