Triazine-cored donor–acceptor covalent organic framework promotes highly efficient photocatalytic synthesis of H2O2

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01754H, Paper
Lihua Li, Xin Yao, Weizhi Ou, Jing Chai, Ru Ma, Chenglong Ran, Anzhi Ma, Xiaojun Shi, Pifeng Wei, Hong Dong, Hongpeng Zhou, Wenbing Yang, Hai-Chao Hu, Jian-Feng Wu, Hui Peng, Guofu Ma
A D–A COF (TPB–TPT-COF) with triazine groups enabled photocatalytic H2O2 production at 6740 μmol g−1 h−1 without sacrificial agents. DFT and experiments show its D–A structure boosts carrier separation and transport for enhanced performance.
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