Acidic CO2 electroreduction to formic acid at low overpotentials over Cu modified with a dual site polymer

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03348A, Paper
Yajuan Wang, Zijun Zhang, Chunjun Chen, Yingxuan Liu, Yichi Zhang, Mingjie Cheng, Xia Bai, Shuaiqiang Jia, Mingyuan He, Haihong Wu, Buxing Han
The FE of HCOOH was enhanced over commercial Cu by the modification with a dual site polymer under acidic conditions. The quaternary ammonium cation promoted CO2 reduction at low potentials, the tertiary amine stabilized the key intermediate *OCHO.
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