The position-tuned nitrogen atom in Ni(II)-metalated covalent organic frameworks enables highly efficient and sustainable C–N coupling

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03438H, Paper
Rui Zhang, Jinyang Hai, Huiying Chen, Mingxiang Zhu, Fang Zhang
Ni@Bpma-COF with highly efficient electron transfer (via regulating the electron transport distance and electron acceptance ability of the metal center) enables efficient and green Buchwald-Hartwig amination reactions.
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