Dual silane-promoted palladium catalysis: synthesis of phenols from carbon dioxide and 1,4-enynes

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Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC05578D, Communication
Zhongrong Xu, Ting Zhao, Wenxin Jiang, Yanwei Ren, Chaorong Qi, Huanfeng Jiang
A unique dual-hydrosilane system enables the palladium-catalyzed reductive carbonylative benzannulation of 3-acetoxy-1,4-enynes with CO2, providing direct access to multi-substituted phenols under operationally simple conditions.
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