Upcycling poly(ε-caprolactone) into azepane via reductive ammonolysis over a titanium oxide-supported platinum catalyst

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Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC00098C, Communication
Open Access Open Access
Daratu E. K. Putri, Katsumasa Sakoda, Yoshiki Takamoto, Sho Yamaguchi, Takato Mitsudome, Tomoo Mizugaki
Poly(ε-caprolactone) (PCL) is selectively upcycled into azepane via reductive ammonolysis using a reusable Pt/TiO2 catalyst, offering a promising contribution to plastic upcycling and nitrogen-based circular economy strategies.
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