Accurately regulating the Ni coordination environment via atomic layer deposition and enabling efficient CO2 electroreduction

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Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC01127F, Paper
Xian Liu, Shuangfeng Xing, Jijie Li, Wen-Yan Zan, Zhe Gao, Fengwei Zhang
The 5Ni@NC-400H catalyst with Ni2N6 sites showed 99.5% of FECO for CO2RR to CO at −0.77 V and FECO retained >99% from −0.37 to −1.17 V vs. RHE in flow cell. The CO2 activation at Ni2N6 sites occurs via bridging absorption of reaction intermediates.
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