Strengthened d–π interaction in bimetallic clusters for boosted urea electrosynthesis from nitrate and CO2 in simulated industrial waste

Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC02382G, Paper

Chunjing Tao, Jingting He, Wei Li, Fanfei Meng, Dongxu Cui, Meiyan Wang, Guogang Shan, Xinlong Wang, Zhongmin Su, Chunyi Sun
The bimetallic cluster Cu^I₄Fe^II, made via heterometallic regulation, shows high activity for electrocatalytic urea synthesis, with 62% FE under pure CO₂/50 mM NO₃⁻ and 41% in a low-concentration environment.
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