Kinetically guided on-demand mCPBA generation enables safe and sustainable light-driven synthesis of Davis reagents

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Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC02210C, Paper
Open Access Open Access
Muthu Karuppasamy, Mohamed S. H. Salem, Kwangkyun Jang, Mitsuhiro Arisawa, Masayuki Kirihara, Shinobu Takizawa
On-demand in situ generation of mCPBA under sunlight enables efficient oxidation of N-sulfonyl imines. Kinetic studies confirm no mCPBA accumulation, minimizing peracid-handling risks and providing a safe and sustainable protocol to Davis reagents.
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