Chemoenzymatic synthesis of amino-esters as precursors of ammonium salt-based surfactants from 5-hydroxymethylfurfural (HMF)

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Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC00425F, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Carlos Moriana Herraiz, Karen S. Arias, Maria J. Climent, Sara Iborra, Avelino Corma
Precursors of ammonium salt biosurfactants have been obtained from HMF by coupling cobalt-catalyzed reductive amination with selective bio-esterification using an immobilized lipase CALB. The process has been optimized in batch and flow reactors.
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