Constructing highly reactive Pd nanoparticles with π bonds in imidazolium-based metal–organic frameworks for chemoselective CO2 multicomponent transformation

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Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC04311E, Paper
Jie Chen, Lingfang Kong, Qinggang Zhang, Wenjing Shi, Shiyong Zhang, Hongen Qu, Guohai Xu, Zhonggao Zhou, Yiwang Chen
A scalable π-bond-stabilized 10%Pd@Er-MOF catalyst drives 100% selective 4C-TCRs of propargylic amines, aryl iodides, and in situ-activated CO2, yielding oxazolidinones with 99% yield and 227 h−1 TOF.
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