Electrochemical sulfinylation-driven skeletal rearrangement of Baylis–Hillman adducts

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Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC05810D, Paper
Indrajit Karmakar, Xiang-Wei Huang, Hsiu-Te Hung, Rekha Bai, Ci-Yang Sun, Chien-Wei Chiang, Chin-Fa Lee
We report an electrochemical sulfinylation protocol that drives a skeletal rearrangement of Baylis–Hillman adducts, enabling the late-stage synthesis of methyl (Z)-3-(aryl/heteroaryl)-2-[(aryl/alkyl)sulfinyl]methyl acrylates.
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