Green epoxidation of unactivated alkenes via the catalytic activation of hydrogen peroxide by 4-hydroxybenzaldehyde

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02537K, Paper
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Efthymios T. Poursaitidis, Christiana Mantzourani, Ierasia Triandafillidi, Maroula G. Kokotou, Christoforos G. Kokotos
An organocatalytic protocol that utilizes 4-hydroxybenzaldehyde as an activator of H2O2 for the epoxidation of unactivated olefins is described. An unprecedented Payne/Dakin tandem mechanistic scenario is presented, supported by DI-HRMS experiments.
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