Metal-free carboxamidation of P(O)H compounds with in situ formed isocyanates from dioxazolones: a convenient access to carbamoylphosphine oxides

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00470E, Paper
Yong Zhao, Longyang Chen, Guohao Xu, Shanshan Meng, Chuan Fu, Pengxiang Xu, Yuxing Gao, Yufen Zhao
A facile and metal-free method for synthesizing structurally diverse carbamoylphosphine oxides from dioxazolones and P(O)H compounds was developed.
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