Metal-free electrohalogenation of olefins with aqueous NaX mediators

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04102C, Communication
Zhe Zhang, Quanjin Rong, Shengkang Qian, Jianyou Zhao, Chengling Deng, Jiaoyang Liu, Fan Wang, Shuai Liu, Zhong-Quan Liu
We have developed a practical and diverse chlorination of alkenes via metal-free electrochemistry. By simply tuning the substitution pattern of the alkene, selective access to vicinal dichlorides, monochlorides, or allylic chlorides can be achieved.
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