Nickel catalyzed hydrodechlorination and CO functionalization of polyvinyl chloride

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Green Chem., 2025, 27,8559-8568
DOI: 10.1039/D5GC01890K, Paper
Ayon Das, Megan E. Fieser
Earth-abundant Ni-catalyzed poly(vinyl chloride) hydrodechlorination leads to a polyethylene like product with in-chain incorporation of carbonyl groups using sodium formate as a source of both H and CO, yielding NaCl as a benign co-product.
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