Photocatalytic radical (O)P–P(O) bond formation: access to diphosphine dioxides for thermoset protection

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Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC07067H, Paper
Zhi-Cheng Fu, Yu Qin, Hong-Jun Yang, Wen-Li An, Ting Wang, Jin-Ni Deng, Ming-Jun Chen
A photocatalytic radical coupling method synthesizes diphosphine dioxides in high yields on a kilogram scale and uses recyclable catalysts/solvents via filtration. Moreover, it achieves thermoset protection in extreme environments.
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