Photoinduced and proton-activated N-heteroarene-catalyzed dioxygen activation for benzylic and allylic oxidation

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03206G, Paper
Jiaxin He, Yue Shi, Haofeng Shi, Jialiang Wu, Kaiyue Yang, Dan Xiao, Genping Huang, Yunfei Du
We present an organic photosensitizer based on a “proton-activation” mode, which could undergo a key energy-transfer process with molecular dioxygen in air to form singlet oxygen, facilitating diversified benzylic oxidation and allylic oxidation.
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