Porphyrin-based metal–organic frameworks anchored with Cu species for highly efficient electrocatalytic CO2 reduction to CH4

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02085A, Paper
Weiqi Cao, Dexin Yang, Bingyu Li, Yulan Mi, Kongsheng Qi, Yidan Mao, Yuhua Zhao, Hongping Li, Zhen-Hong He
The Cu-PMOF showed excellent selectivity for the electroreduction of CO2 to CH4, reaching a peak Faradaic efficiency of 80.4% at −300 mA cm−2 and achieving a maximum partial current density of −337.5 mA cm−2 at −1.23 V versus RHE.
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