Thiyl chemistry: cysteine-catalyzed maleate isomerization via aqueous thiyl radical processes

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Green Chem., 2025, Advance Article
DOI: 10.1039/D4GC06310D, Paper
Satoru Kosaka, Kentaro Kurebayashi, Naoki Yamato, Hiroshi Tanaka, Naoki Haruta, Masanori Yamamoto
An electron-deficient thiyl radical, with the reactivity complementary to thiolates, for molecular catalysis of maleate isomerization in aqueous solutions.
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