Unveiling the five-membered ring structures in “soft” coke deposits on Fe–Ni catalysts: formation mechanisms and implications for biomass catalytic reforming

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02932E, Paper
Wenkai Lang, Jin Deng, Xin Liu, Zaiyu Yang, Ruxia Zhang, Honghong Liu, Keyuan Sun, Shenfu Yuan
A five-membered ring structure in coke deposits was proposed, and cyclopentanone was identified as the key intermediate in the formation of this structure. The reaction mechanism from real biomass to catalyst coke deposits was sorted out.
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