Visible light-mediated organocatalyzed 1,2-sulfonylation/acylation cascade of allenes for stereodefined tetrasubstituted alkenes

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Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC02060G, Paper
Jiuli Xia, Kehan Jiao, Yunliang Guo, Dongyu Yao, Lihan Zhu, Guangfan Zheng, Jiaqiong Sun, Tao Xiong, Qian Zhang
Visible-light-driven NHC/PC dual catalysis promotes the 1,2-monofluoromethylsulfonylation/acylation of allenes under mild conditions with high regio-, chemo-, and E/Z selectivity, delivering stereodefined tetrasubstituted alkene scaffolds.
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