Engineering nickel catalysts with atomic-sulfur-stabilized thiolate adlayers for durable selectivity in hydrogenation of halonitrobenzenes

Green Chem., 2026, 28,5780-5787
DOI: 10.1039/D5GC06883E, Paper

Yujian Fan, Xuechun Sang, Juwen Gu, Qian Zhang, Songbai Qiu, Tiejun Wang
Durable Ni catalyst with atomic-sulfur critically stabilized thiolate adlayers achieves >99.9% selectivity in halonitrobenzene hydrogenation via upright adsorption, suppressing dehalogenation for minimal waste and high atom economy.
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