An ionic porous organic polymer gel with hydroxide anions as an efficient catalyst for N-formylation of amines and amides with carbon dioxide

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00173K, Paper
Jie Xu, Di Chen, Zhaobin Ye, Shasha Ma, Yuanlong Wang, Jianyong Zhang
A metal-free heterogeneous ionic gel catalyst with triaminoguanidine and 1,1′-(p-phenylenedimethylene)bis(4-formylpyridinium) cationic units catalyzes the N-formylation of amines and amides.
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