Degradation of sulfur hexafluoride and its application in the synthesis of esters and amides

Green Chem., 2025, Advance Article
DOI: 10.1039/D4GC05318D, Paper

Yifeng Chen, Shiyu Gu, Yue Zhao, Yi You, Fengxiang Ma, Feng Zhu, Shan Zhu, Lan-Gui Xie
The reaction utilizing sulfur tetrafluoride (SF₄) and thionyl fluoride (SOF₂) generated from the photoredox catalytic reduction of the greenhouse gas SF₆ to facilitate esterification and amidation of carboxylic acids is presented.
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