Electron-deficient Mo sites enhance electrochemical nitrate reduction to ammonia by promoting water dissociation

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01249J, Paper
Xue Zhou, Wence Xu, Yunduo Huang, Zhonghui Gao, Yanqin Liang, Hui Jiang, Zhaoyang Li, Fang Wang, Shengli Zhu, Zhenduo Cui
Nanoporous Mo-doped Co2P exhibits outstanding NITRR performance, as the introduction of electron-deficient Mo promotes H2O dissociation to *H, enabling efficient NO hydrogenation with nearly 100% NH3 FE and 40.6% EE at −0.1 V vs. RHE.
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