Transition metal/photocatalyst-free synthesis of geminal diamines via a sandwich-like photoactive donor–acceptor–donor complex

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00426H, Paper
Ziyi Xu, Ziyang Chen, Shuyang Liu, Jian Gao, Jinglan Lei, Min Li, Yongqiang Zhang, Ziyu Gan, Limei Yu, Shu-Xin Liu, Yunhe Jin
A transition metal/photocatalyst-free access to geminal diamines is realized conveniently through an unusual sandwich-like ternary donor–acceptor–donor complex resulting from π–π stacking and base action.
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