Enhanced production of dimethyl carbonate from the alternating polarity electrolysis of methanol and carbon dioxide

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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02358K, Communication
Open Access Open Access
Momoko Ishii, Maria M. Paulsen, Remi A. Mellinghoff, Heather O. LeClerc, Ho Yin Tse, Hanno C. Erythropel, Julie B. Zimmerman, Paul T. Anastas, Darren S. Lee
Alternating polarity enhanced redox-neutral electrochemical formation of dimethyl carbonate (DMC) from CO2 and methanol. Alternating the polarity was found to be necessary for efficient reoxidation of Pd0 → Pd2+ thus enabling higher yields of DMC.
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