Harnessing solvent–3O2 charge transfer complex for photochemical conversion of phosphines to phosphine oxides: the synergy of light and ambient air

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Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC00878J, Communication
Rahul Mondal, Reetu Rani Mondal, K. Geetharani
We report a catalyst-free photo-oxidation of phosphines via direct excitation of a solvent-O2 charge-transfer complex. Using ambient air, a green solvent and a near-UV LED, this offers broad scope, high atom economy, and gram-scale efficiency.
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